Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc

In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination en...

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Bibliographic Details
Main Authors: Hisham, N.A.I., Ali, H.M., Khaledi, H.
Format: Article
Published: 2011
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Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022021
http://scripts.iucr.org/cgi-bin/paper?S1600536811022021
http://eprints.um.edu.my/5232/1/Hisham%2D2011%2DDichlorido(2%2D%7B_3%2D(mo.pdf
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Summary:In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed.