Tetra-mu(2)-acetato-bis{mu(2)-5-methoxy-2- (2-morpholinoethyl)iminiometh yl phenolato}tricadmium(II)
The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry....
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
2009
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| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809029171 http://scripts.iucr.org/cgi-bin/paper?S1600536809029171 http://eprints.um.edu.my/5384/1/Lair%2D2009%2DTetra%2Dmu(2)%2Dacetato%2D.pdf |
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| Summary: | The central Cd-II atom in the trinuclear title compound, [Cd-3(C14H19N2O3)(2)(CH3COO)(4)], lies on a center of inversion and is bonded to the O atoms of four acetate groups as well as to the phenolate O atoms of the mono-deprotonated Schiff base ligands in a distorted all-trans octahedral geometry. Two of the acetate groups function in a mu(2)-bridging mode, while the other two each chelate to the terminal Cd-II atom and simultaneously bind to the central metal atom in a kappa(3)-bonding mode. The Schiff base anions N,O-chelate to the terminal metal atoms. The morpholine ring assumes a chair conformation. |
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