Synthesis and Characterization of Polyurethane–Organoclay Nanocomposites Based on Renewable Castor Oil Polyols

In this study, castor oil-based polyurethanes–organoclay (COPUs-Cloisite 30B) nanocomposites are synthesized by mixing polypropylene glycol polyol and dehydrated castor oil (15 %), enforced with C30B nanofillers, at different weight percentages. The physico-chemical behaviors were evaluated by Fouri...

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Bibliographic Details
Main Authors: M. A., Alaa, Kamal, Yusoh, S. F., Hasany
Format: Article
Published: Springer Berlin Heidelberg 2015
Subjects:
Online Access:http://dx.doi.org/10.1007/s00289-014-1255-6
http://dx.doi.org/10.1007/s00289-014-1255-6
http://umpir.ump.edu.my/12384/1/Synthesis%20and%20characterization%20of%20polyurethane-organoclay%20nanocomposites%20based%20on%20renewable%20castor%20oil%20polyols.pdf
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Summary:In this study, castor oil-based polyurethanes–organoclay (COPUs-Cloisite 30B) nanocomposites are synthesized by mixing polypropylene glycol polyol and dehydrated castor oil (15 %), enforced with C30B nanofillers, at different weight percentages. The physico-chemical behaviors were evaluated by Fourier transform infrared spectroscopy, Fourier scanning electron microscopy, scanning electron microscopy and X-ray diffraction. Thermal stability was found improved up to ~30 °C in the sample with 5 wt% of C30B. Tensile properties depicted an improvement of ~240 % in tensile strength and decrease of ~30 % in elongation with 5 wt% organoclay, respectively. Improved physico-chemical properties of COPUs-C30B signify the usage of COPUs-C30B in the industrial and commercial applications, i.e. coatings, adhesives and automotive applications.