Heck, Suzuki and Sonogashira Cross-coupling Reactions using ppm level of SBA-16 supported Pd-complex
SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently pr...
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Royal Society of Chemistry
2015
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| பகà¯à®¤à®¿à®•à®³à¯: | |
| நிகழà¯à®¨à®¿à®²à¯ˆ அணà¯à®•à®²à¯: | http://dx.doi.org/10.1039/C4NJ02319F http://dx.doi.org/10.1039/C4NJ02319F http://umpir.ump.edu.my/12768/1/New%20J%20Chem.pdf |
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| தொகà¯à®ªà¯à®ªà¯: | SBA-16 supported 1,2-diaminocyclohexane Pd-complex (100–500 mol ppm of Pd) was found to be an efficient catalyst in the palladium-catalyzed Mizoroki–Heck, Suzuki–Miyaura and copper-free Sonogashira cross-coupling reactions of aryl halides under mild reaction conditions. The Pd-complex efficiently promoted all of these coupling reactions with appropriate coupling partners to afford the corresponding
coupling products with almost quantitative yield. The supported Pd-complex was readily recovered and
used five times without a significant loss of its catalytic activity. |
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