Hydrothermal growth of bilayered rutile-phased TiO2 nanorods/micro-sizeTiOz flower in highly acidic solution for dye-sensitized solar cell

Aligned rutile-phased TiO2 (r-TNRs) nanorods and micro-size rutile-phased TiO2 flowers (r-TFs) films were prepared on fluorinedoped tin oxide (FIO) substrate using highly acidic solution by two steps of hydrothermal process. The hydrothermal process was done at 150'C in 5 h for the first step a...

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Bibliographic Details
Main Authors: Ahmad, Mohd Khairul, Mohan, V. M., Murakami, K.
Format: Article
Published: Springer 2015
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Online Access:http://link.springer.com/10.1007/s10971-015-3615-6
http://link.springer.com/10.1007/s10971-015-3615-6
http://eprints.uthm.edu.my/6859/1/Mohd_Khairul_Ahmad_U.pdf
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Summary:Aligned rutile-phased TiO2 (r-TNRs) nanorods and micro-size rutile-phased TiO2 flowers (r-TFs) films were prepared on fluorinedoped tin oxide (FIO) substrate using highly acidic solution by two steps of hydrothermal process. The hydrothermal process was done at 150'C in 5 h for the first step and 2 h for the second step. These films were used as a photoelectrode in dye-sensitized solar cell (DSC) application. Aligned r-TNRs and r-TFs were prepared using one-step and two-step hydrothermal processes, respectively. At the end of second step hydrothermal process, micro-size rutile-phased TiO2 flowers (r-TFs) were observed on top of r-TNRs (FTO/r-TNRs/r-TFs). Power conversion efficiencies for both aligned r-TNRs and r-TNRs/r-TFs were compared. From the results, DSC made of r-TNRs only produced energy conversion efficiency of 1.52 Va and DSC made of r-TNRs/r-TFs gave excellent energy conversion efficiency (fi of 4.27 7o.