Kinetics of radiation-induced graft copolymerization of vinylbenzyl chloride onto nylon fibers
The graft copolymerization of vinylbenzyl chloride (VBC) onto nylon-6 fiber was investigated by the pre-irradiation method using electron beam. The effects of grafting parameters, monomer concentration, absorbed dose and reaction temperature were investigated. The empirical kinetic rate equation dGo...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Conference or Workshop Item |
| Published: |
2015
|
| Subjects: | |
| Online Access: | http://eprints.utm.my/60828/ http://eprints.utm.my/60828/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The graft copolymerization of vinylbenzyl chloride (VBC) onto nylon-6 fiber was investigated by the pre-irradiation method using electron beam. The effects of grafting parameters, monomer concentration, absorbed dose and reaction temperature were investigated. The empirical kinetic rate equation dGo/dt=k[M]^0.86*[D]^1.06 was used to describe grafting of VBC onto nylon-6. The overall activation energy for graft copolymerization of VBC was found to be 22.6 kJ/mol. The results revealed that the grafting kinetic was controlled by the amounts of trapped radicals and monomer molecules. Fourier transform infrared (FT-IR) was used to provide evidence for the formation of grafted copolymers. |
|---|