Oxygen vacancy-rich mesoporous silica kcc-1 for CO2 methanation
Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous s...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Published: |
Elsevier
2017
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| Subjects: | |
| Online Access: | http://eprints.utm.my/66120/ http://eprints.utm.my/66120/ http://eprints.utm.my/66120/ |
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| Summary: | Mesoporous silica KCC-1 was successfully synthesized by microemulsion system coupled with microwave-assisted hydrothermal method. Mesoporous silica KCC-1 exhibited spherical morphology surrounded with dendritic fiber with the particle size of 200–400 nm and BET surface area of 773 m2/g. Mesoporous silica KCC-1 has significantly higher number of basicity and oxygen vacancy than those of MCM-41 and SiO2 which directly correlated with the catalytic performance of the catalyst. The activity of mesoporous silica KCC-1 in CO2 methanation is five-fold higher than MCM-41 with the yield of CH4 reached 38.9% at 723 K. |
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